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Effect of placement angles on wireless electrocoagulation for bipolar aluminum electrodes

Zhenlian Qi, Jinna Zhang, Shijie You

《环境科学与工程前沿（英文）》 2018年 第12卷 第3期 doi: 10.1007/s11783-018-1034-y

摘要： We in our previous study reported the wireless electrocoagulation (WEC) based on bipolar electrochemistry for water purification. One of the most important advantages of WEC is the omission of ohmic connection between bipolar electrode (BPE) and power supply, and thus the electrochemical reactions on BPE are driven by electric field in solution induced by driving electrodes. In this study, the impact of placement angle of bipolar aluminum electrode on WEC was investigated to provide a detailed analysis on the correlations between the bipolar electrode placement angle and bipolar electrocoagulation reactions. The results showed that the WEC cell with a horizontal BPE placed at 0° produced the maximum dissolved aluminum coagulant, accounting for 71.6 % higher than that with a vertical one placed at 90°. Moreover, the finite element simulations of current and potential distribution were carried out along the surface of BPE at different placement angles, revealing the mechanism of different BPE placement angles on aluminum dissolution rates in WEC system.

关键词： Bipolar electrochemistry     Wireless electrocoagulation     Placement angle    

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mechanistic study on electrocoagulation process for municipal wastewater treatment based on horizontal bipolar

Zhenlian Qi, Shijie You, Ranbin Liu, C. Joon Chuah

《环境科学与工程前沿（英文）》 2020年 第14卷 第3期 doi: 10.1007/s11783-020-1215-3

摘要： EC modified with BPEs enhances pollutant removal and reduce energy consumption. Increasing BPE number cannot increase flocculants yield exponentially. Simulations help to predict the distribution of electrochemical reactions on BPEs. The design of electrodes is crucial to electrocoagulation process (EC), specifically, with respect to pollutant removal and energy consumption. During EC, the mechanisms for interaction between different electrode arrangement and electrode reactions remain unclear. This work presents an integrated EC process based on horizontal bipolar electrodes (BPEs). In the electrochemical cell, the graphite plates are used as driving cathode while either Fe or Al plates serves as driving anode and BPEs. The BPEs are placed horizontally between the driving electrodes. For municipal wastewater treatment, the pollutant removal efficiency and energy consumption in different configurations of two-dimension electrocoagulation (2D-EC) system with horizontal BPEs were investigated. The removal efficiency of turbidity, total phosphorus and total organic carbon increased significantly with the number of BPEs. Noted that the energy consumption for TP removal decreased by 75.2% with Fe driving anode and 81.5% with Al driving anode than those of 2D-EC, respectively. In addition, the physical field simulation suggested the distributions of potential and current in electrolyte and that of induced charge density on BPE surface. This work provides a visual theoretical guidance to predict the distribution of reactions on BPEs for enhanced pollutant removal and energy saving based on electrocoagulation process for municipal wastewater treatment.

关键词： Electrocoagulation     Bipolar electrodes     Municipal wastewater     Simulations    

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Research progress in tribo-electrochemistry and tribo-electrochemical polishing

ZHAI Wenjie

《机械工程前沿（英文）》 2007年 第2卷 第4期   页码 463-467 doi: 10.1007/s11465-007-0080-0

摘要： In this paper, the status quo and recent progress in the research on tribo-electrochemistry in aqueous and non-aqueous media, respectively, are reviewed. Much more attention has been paid to the tribo-electrochemical mechanisms for the control of friction and wear. Based on a summary of the conventional polishing principles of hard and brittle materials, the tribo-electrochemical polishing method is proposed. The results of the preliminary test show that tribo-electrochemical polishing is promising to become a critical technology in the high efficient polishing and planarization of microelectronic materials.

关键词： tribo-electrochemical mechanisms     planarization     non-aqueous     tribo-electrochemistry     summary    

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The treatment of black-odorous water using tower bipolar electro-flocculation including the removal of

Huan He, Qinjin Yu, Chaochao Lai, Chen Zhang, Muhan Liu, Bin Huang, Hongping Pu, Xuejun Pan

《环境科学与工程前沿（英文）》 2021年 第15卷 第2期 doi: 10.1007/s11783-020-1310-5

摘要： Abstract • An innovative bubble column tower BPE was designed to treat the black-odorous water. • PO43−, S2− and turbidity were removed, and dissolved oxygen was enriched in the BPE. • An aluminum bipolar electrode gave the best oxygen enrichment and pollutant removal. • Changes of microorganisms confirmed the improvement in water quality achieved. The large amount of municipal wastewater discharged into urban rivers sometimes exceeds the rivers’ self-purification capacity leading to black-odorous polluted water. Electro-flocculation has emerged as a powerful remediation technology. Electro-flocculation in a bubble column tower with a bipolar electrode (BPE) was tested in an attempt to overcome the high resistance and weak gas-floatation observed with a monopolar electrode (MPE) in treating such water. The BPE reactor tested had a Ti/Ta2O5-IrO2 anode and a graphite cathode with an iron or aluminum bipolar electrode suspended between them. It was tested for its ability to reduce turbidity, phosphate and sulphion and to increase the concentration of dissolved oxygen. The inclusion of the bipolar electrode was found to distinctly improved the system’s conductivity. The system’s electro-flocculation and electrical floatation removed turbidity, phosphate and sulphion completely, and the dissolved oxygen level improved from 0.29 to 6.28 mg/L. An aluminum bipolar electrode performed better than an iron one. Changes in the structure of the microbial community confirmed a significant improvement in water quality.

关键词： Black-odorous water     Bipolar electrodes     Flocculation     Floatation     Oxygen enrichment     Turbidity    

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Multistage-batch bipolar membrane electrodialysis for base production from high-salinity wastewater

《化学科学与工程前沿（英文）》 2022年 第16卷 第5期   页码 764-773 doi: 10.1007/s11705-021-2114-2

摘要： Bipolar membrane electrodialysis (BMED) is considered a state-of-the-art technology for the conversion of salts into acids and bases. However, the low concentration of base generated from a traditional BMED process may limit the viability of this technology for a large-scale application. Herein, we report an especially designed multistage-batch (two/three-stage-batch) BMED process to increase the base concentration by adjusting different volume ratios in the acid (Vacid), base (Vbase), and salt compartments (Vsalt). The findings indicated that performance of the two-stage-batch with a volume ratio of Vacid:Vbase:Vsalt = 1:1:5 was superior in comparison to the three-stage-batch with a volume ratio of Vacid:Vbase:Vsalt = 1:1:2. Besides, the base concentration could be further increased by exchanging the acid produced in the acid compartment with fresh water in the second stage-batch process. With the two-stage-batch BMED, the maximum concentration of the base can be obtained up to 3.40 mol∙L–1, which was higher than the most reported base production by BMED. The low energy consumption and high current efficiency further authenticate that the designed process is reliable, cost-effective, and more productive to convert saline water into valuable industrial commodities.

关键词： bipolar membrane electrodialysis     multistage-batch     base production     high-salinity wastewater    

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Study on tribological and electrochemistry properties of metal materials in H2O2 solutions

Chengqing YUAN, Li YU, Jian LI, Xinping YAN

《机械工程前沿（英文）》 2012年 第7卷 第1期   页码 93-98 doi: 10.1007/s11465-012-0313-8

摘要：

Hydrogen peroxide (H2O2) is a kind of ideal green propellant. It is crucial to study the wear behavior and failure modes of the metal materials under the strong oxidizing environment of H2O2. This study aims to investigate the wear of rubbing pairs of 2Cr13 stainless steel against 1045 metal in H2O2 solutions, which has a great effect on wear, the decomposition and damage mechanism of materials. The comparison analysis of the friction coefficients, wear mass loss, worn surface topographies and current densities was conducted under different concentrations of H2O2 solutions. There were significant differences in the tribological and electrochemistry properties of the rubbing pairs in different H2O2 solutions.

关键词： hydrogen peroxide     wear     corrosion     wear mechanism    

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Performance of activated carbon coated graphite bipolar electrodes on capacitive deionization method

Hossein D. Atoufi, Hasti Hasheminejad, David J. Lampert

《环境科学与工程前沿（英文）》 2020年 第14卷 第6期 doi: 10.1007/s11783-020-1278-1

摘要： Abstract • Graphite bipolar electrodes act as an appropriate bed for the CDI process. • Activated carbon Coating improves the application of the electrodes. • CDI is an environmentally friendly method to apply for brackish water. • Initial concentration is the most important parameter in the CDI method. • CDI process in a batch-mode setup needs more development. This research investigates a capacitive deionization method for salinity reduction in a batch reactor as a new approach for desalination. Reductions of cost and energy compared with conventional desalination methods are the significant advantages of this approach. In this research, experiments were performed with a pair of graphite bipolar electrodes that were coated with a one-gram activated carbon solution. After completing preliminary tests, the impacts of four parameters on electrical conductivity reduction, including (1) the initial concentration of feed solution, (2) the duration of the tests, (3) the applied voltage, and (4) the pH of the solution, were examined. The results show that the maximum efficiency of electrical conductivity reduction in this laboratory-scale reactor is about 55%. Furthermore, the effects of the initial concentration of feed solution are more significant than the other parameters. Thus, using the capacitive deionization method for water desalination with low and moderate salt concentrations (i.e., brackish water) is proposed as an affordable method. Compared with conventional desalination methods, capacitive deionization is not only more efficient but also potentially more environmentally friendly.

关键词： Capacitive deionization (CDI)     Desalination     Electrical conductivity (EC)     Graphite bipolar electrode     Activated carbon coated (ACC)    

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8英寸绝缘栅双极型晶体管 (IGBT) 关键技术研究 Article

刘国友,丁荣军,罗海辉

《工程（英文）》 2015年 第1卷 第3期   页码 361-366 doi: 10.15302/J-ENG-2015043

摘要：

基于8英寸绝缘栅双极型晶体管 (IGBT) 生产线的建设，重点解决了8英寸IGBT先进工艺技术、第四代高压双扩散金属氧化物半导体 (DMOS+) IGBT技术和第五代沟槽栅IGBT技术等关键技术问题，实现了高压IGBT芯片制造从6英寸到8英寸的技术突破，自主开发的1600 A/1.7 kV与1500 A/3.3 kV IGBT模块已经被成功制造并通过考核，现已应用于轨道交通牵引系统。

关键词： 绝缘栅双极型晶体管 (IGBT)     高功率密度     沟槽栅     8英寸     轨道交通    

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Enabling nickel ferrocyanide nanoparticles for high-performance ammonium ion storage

《化学科学与工程前沿（英文）》 2023年 第17卷 第2期   页码 226-235 doi: 10.1007/s11705-022-2198-3

摘要： Prussian blue and its analogs are extensively investigated as a cathode for ammonium-ion batteries. However, they often suffer from poor electronic conductivity. Here, we report a Ni2Fe(CN)6/multiwalled carbon nanotube composite electrode material, which is prepared using a simple coprecipitation approach. The obtained material consists of nanoparticles with sizes 30–50 nm and the multiwalled carbon nanotube embedded in it. The existence of multiwalled carbon nanotube ensures that the Ni2Fe(CN)6/multiwalled carbon nanotube composite shows excellent electrochemical performance, achieving a discharge capacity of 55.1 mAh·g–1 at 1 C and 43.2 mAh·g–1 even at 15 C. An increase in the ammonium-ion diffusion coefficient and ionic/electron conductivity based on kinetic investigations accounts for their high performance. Furthermore, detailed ex situ characterizations demonstrate that Ni2Fe(CN)6/multiwalled carbon nanotube composite offers three advantages: negligible lattice expansion during cycling, stable structure, and the reversible redox couple. Therefore, the Ni2Fe(CN)6/multiwalled carbon nanotube composite presents a long cycling life and high rate capacity. Finally, our study reports a desirable material for ammonium-ion batteries and provides a practical approach for improving the electrochemical performance of Prussian blue and its analogs.

关键词： nickel ferrocyanides     NH4+     electrochemistry     Prussian blue     aqueous ammonium ion batteries    

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Electrochemical CO reduction to C products over CuZn intermetallic catalysts synthesized by electrodeposition

《能源前沿（英文）》 doi: 10.1007/s11708-023-0898-0

摘要： Electrocatalytic CO2 reduction (ECR) offers an attractive approach to realizing carbon neutrality and producing valuable chemicals and fuels using CO2 as the feedstock. However, the lack of cost-effective electrocatalysts with better performances has seriously hindered its application. Herein, a one-step co-electrodeposition method was used to introduce Zn, a metal with weak *CO binding energy, into Cu to form Cu/Zn intermetallic catalysts (Cu/Zn IMCs). It was shown that, using an H-cell, the high Faradaic efficiency of C2+ hydrocarbons/alcohols (FEC2+) could be achieved in ECR by adjusting the surface metal components and the applied potential. In suitable conditions, FEC2+ and current density could be as high as 75% and 40 mA/cm2, respectively. Compared with the Cu catalyst, the Cu/Zn IMCs have a lower interfacial charge transfer resistance and a larger electrochemically active surface area (ECSA), which accelerate the reaction. Moreover, the *CO formed on Zn sites can move to Cu sites due to its weak binding with *CO, and thus enhance the C–C coupling on the Cu surface to form C2+ products.

关键词： carbon dioxide electroreduction     electrochemistry     co-electrodeposition     intermetallic catalysts     value-added chemicals    

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质子交换膜燃料电池的研究进展

任学佑

《中国工程科学》 2005年 第7卷 第1期   页码 86-94

摘要：

论述了质子交换膜燃料电池的开发现状及国内外研究进展；同时介绍了趋于成熟的贮氢技术，包括质子交换膜、双极板、膜电极和电催化剂在内的关键技术、应用以及未来展望。

关键词： 燃料电池     质子交换膜     双极板     膜电极     电催化剂     开发现状    

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流体电化学靶向诱生硫酸根自由基降解水中微污染物 Article

郑文天, 尤世界, 姚远, 任南琪, 丁彬, 李方, 刘艳彪

《工程（英文）》 2023年 第30卷 第11期   页码 144-152 doi: 10.1016/j.eng.2022.12.005

摘要：

水中微污染物的深度去除是环境工程领域的重大挑战。受限于低浓度和高毒性等污染特征，传统水处理策略难以实现这类污染物的有效去除。基于此，本文提出了流体电化学靶向诱生硫酸根自由基（SO4•–）的研究设想，通过构筑穿透式电化学反应系统，实现了阳极将硫酸根离子（SO42−）氧化生成过硫酸根（S2O82−），再通过阴极还原反应将S2O82−转化为SO4•–。开展了流体电化学系统构造原理、硫酸根自由基靶向生成机制和微污染物降解机理等相关研究。结果表明，在最优实验条件下，该系统可在单次流模式下实现苯胺的高效降解（100%）和总有机碳的有效去除（65.0%）。该系统在宽pH范围内和复杂水基质条件下均能实现多种微污染物的有效去除。本工作基于“以废治废”理念，结合了膜分离和电化学的技术优势，有望为水中微污染物的深度去除提供一种潜在可行的技术选择。

关键词： 高级氧化     链式反应     硫酸根离子     微污染物     顺序电化学体系    

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nanoparticle decorated N-doped carbons derived from a cobalt covalent organic framework for oxygen electrochemistry

《化学科学与工程前沿（英文）》 2021年 第15卷 第6期   页码 1550-1560 doi: 10.1007/s11705-021-2104-4

摘要： The low cost and highly efficient construction of electrocatalysts has attracted significant attention owing to the use of clean and sustainable energy technologies. In this work, cobalt nanoparticle decorated N-doped carbons (Co@NC) are synthesized by the pyrolysis of a cobalt covalent organic framework under an inert atmosphere. The Co@NC demonstrates improved electrocatalytic capabilities compared to N-doped carbon without the addition of Co nanoparticles, indicating the important role of cobalt. The well-dispersed active sites (Co-Nx) and the synergistic effect between the carbon matrix and Co nanoparticles greatly enhance the electrocatalytic activity for the oxygen reduction reaction. In addition, the Co content has a significant effect on the catalytic activity. The resulting Co@NC-0.86 exhibits a superb electrocatalytic activity for the oxygen reduction reaction in an alkaline electrolyte in terms of the onset potential (0.90 V), half-wave potential (0.80 V) and the limiting current density (4.84 mA·cm–2), and a high selectivity, as well as a strong methanol tolerance and superior durability, these results are comparable to those of the Pt/C catalyst. Furthermore, the superior bifunctional activity of Co@NC-0.86 was also confirmed in a home-built Zn-air battery, signifying the possibility for application in electrode materials and in current energy conversion and storage devices.

关键词： cobalt embedment     N-doped carbons     covalent organic framework     oxygen reduction     Zn-air battery    

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国际电化学学会第70届年会（70th Annual Meeting of the International Society of Electrochemistry）

会议日期： 2019年08月04日

会议地点： 南非/德班

主办单位： 国际电化学学会（ISE）

Metal phosphonate-derived cobalt/nickel phosphide@N-doped carbon hybrids as efficient bifunctional oxygen electrodes for Zn−air batteries

《化学科学与工程前沿（英文）》 2022年 第16卷 第9期   页码 1367-1376 doi: 10.1007/s11705-022-2153-3

摘要： The exploration of efficient bifunctional electrocatalysts for oxygen reduction reaction and oxygen evolution reaction is pivotal for the development of rechargeable metal–air batteries. Transition metal phosphides are emerging as promising catalyst candidates because of their superb activity and low cost. Herein, a novel metal phosphonate-derived cobalt/nickel phosphide@N-doped carbon hybrid was developed by a carbothermal reduction of cobalt/nickel phosphonate hybrids with different Co/Ni molar ratios. The metal phosphonate derivation method achieved an intimately coupled interaction between metal phosphides and a heteroatom-doped carbon substrate. The resultant Co2P/Ni3P@NC-0.2 enables an impressive electrocatalytic oxygen reduction reaction activity, comparable with those of state-of-the-art Pt/C catalysts in terms of onset potential (0.88 V), 4e‒ selectivity, methanol tolerance, and long-term durability. Moreover, remarkable oxygen evolution reaction activity was also observed in alkaline conditions. The high activity is ascribed to the N-doping, abundant accessible catalytic active sites, and the synergistic effect among the components. This work not only describes a high-efficiency electrocatalyst for both oxygen reduction reaction and oxygen evolution reaction, but also highlights the application of metal phosphonate hybrids in fabricating metal phosphides with tunable structures, which is of great significance in the energy conversion field.

关键词： metal phosphonate     cobalt/nickel phosphide     N-doped carbon     oxygen electrochemistry     Zn−air battery    

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标题 作者 时间 类型 操作

Effect of placement angles on wireless electrocoagulation for bipolar aluminum electrodes

Zhenlian Qi, Jinna Zhang, Shijie You

期刊论文

mechanistic study on electrocoagulation process for municipal wastewater treatment based on horizontal bipolar

Zhenlian Qi, Shijie You, Ranbin Liu, C. Joon Chuah

期刊论文

Research progress in tribo-electrochemistry and tribo-electrochemical polishing

ZHAI Wenjie

期刊论文

The treatment of black-odorous water using tower bipolar electro-flocculation including the removal of

Huan He, Qinjin Yu, Chaochao Lai, Chen Zhang, Muhan Liu, Bin Huang, Hongping Pu, Xuejun Pan

期刊论文

Multistage-batch bipolar membrane electrodialysis for base production from high-salinity wastewater

期刊论文

Study on tribological and electrochemistry properties of metal materials in H2O2 solutions

Chengqing YUAN, Li YU, Jian LI, Xinping YAN

期刊论文

Performance of activated carbon coated graphite bipolar electrodes on capacitive deionization method

Hossein D. Atoufi, Hasti Hasheminejad, David J. Lampert

期刊论文

8英寸绝缘栅双极型晶体管 (IGBT) 关键技术研究

刘国友,丁荣军,罗海辉

期刊论文

Enabling nickel ferrocyanide nanoparticles for high-performance ammonium ion storage

期刊论文

Electrochemical CO reduction to C products over CuZn intermetallic catalysts synthesized by electrodeposition

期刊论文

质子交换膜燃料电池的研究进展

任学佑

期刊论文

流体电化学靶向诱生硫酸根自由基降解水中微污染物

郑文天, 尤世界, 姚远, 任南琪, 丁彬, 李方, 刘艳彪

期刊论文

nanoparticle decorated N-doped carbons derived from a cobalt covalent organic framework for oxygen electrochemistry

期刊论文

国际电化学学会第70届年会（70th Annual Meeting of the International Society of Electrochemistry）

2019年08月04日

会议信息

Metal phosphonate-derived cobalt/nickel phosphide@N-doped carbon hybrids as efficient bifunctional oxygen electrodes for Zn−air batteries

期刊论文